GCSE Chemistry, Unit 4, Lesson 5 of 7

Electrolysis of melts and solutions

GCSE Chemistry, Chemical changes: reactivity, acids and electrolysis, 20 minutes

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How a current splits an ionic compound, what forms at each electrode when it is molten, and the rules for which products form from a solution.

What you will learn

  • Explain why an ionic compound must be molten or dissolved to be electrolysed
  • Name the products at each electrode for a molten compound
  • Predict the products from an aqueous solution
  • Say what is left in the solution afterwards

What electrolysis does

An ionic compound conducts electricity only when it is molten or dissolved: then its ions are free to move.

This liquid is the electrolyte.

d.c. supply−+++−−cathode (−)anode (+)electrolyte
  • Positive ions move to the cathode (negative electrode) and gain electrons.
  • Negative ions move to the anode (positive electrode) and lose electrons.
  • The electrodes are usually inert (graphite or platinum), so they do not react.

The rest of this lesson and its 9 practice questions are locked.

In this lesson

  1. What electrolysis does
  2. Molten compounds
  3. Aqueous solutions

9 practice questions, marked as you go; about 20 minutes in all.

Key terms

Electrolyte, Cathode, Anode, Inert, Metal at the cathode, Non-metal at the anode

In this unit: Chemical changes: reactivity, acids and electrolysis

The reactivity series and metal extraction, oxidation and reduction, acids, salts and pH, titrations, and electrolysis of melts and solutions.

All of Chemical changes: reactivity, acids and electrolysis