GCSE Chemistry, Unit 4, Lesson 5 of 7
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Electrolysis of melts and solutions

GCSE Chemistry, Chemical changes: reactivity, acids and electrolysis, 20 minutes

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How a current splits an ionic compound, what forms at each electrode when it is molten, and the rules for which products form from a solution.

What electrolysis does

An ionic compound conducts electricity only when it is molten or dissolved: then its ions are free to move.

This liquid is the electrolyte.

d.c. supply−+++−−cathode (−)anode (+)electrolyte
  • Positive ions move to the cathode (negative electrode) and gain electrons.
  • Negative ions move to the anode (positive electrode) and lose electrons.
  • The electrodes are usually inert (graphite or platinum), so they do not react.

The rest of this lesson and its 9 practice questions are in Plus.

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  • 9 exam-style questions, marked as you go, each with a worked solution
  • Anything you get wrong is saved to your flashcards